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Food industry is facing increasing risks in sustaining itself because of safety concerns sprouting up every day due to new discoveries and emerging knowledge in food science and toxicology. Never heard of chemicals such as Acrylamide have been in the news during the last one decade with no definite conclusions from the scientific community regarding the extent of threat perception posed by these newly "focused" chemical artifacts produced during processing. Unfortunately in spite of consistent efforts in several countries, Acrylamide, formed in many foods during thermal processing under low moisture conditions, has not been established as a threat to consumer safety. It may be recalled that Acrylamide was detected in many foods by Swedish scientists in 2002 and since then thousands of publications appeared, covering practically all aspects of this chemical. Those foods containing the amino acid Asparagine and high starches were found to generate Acrylamide under frying and baking temperatures, probably through the well known Maillard reaction route or the "browning" phenomenon. Though many scary stories emerged regarding its role in human cancers in nervous system, oral cavity, peritoneum, thyroid gland, mammalian gland, uterus etc, these claims were found to based on experiments in animals like mice using doses 900 times higher than possible exposure by humans through the industry produced food products like potato chips!
Food safety is a holy cow and it is very common to talk about the food safety, giving the benefit always to consumer activists who articulate such concerns. Logic is often thrown to winds when tall claims are made regarding safety of foods and ingredients that go into the food during its making. It is often forgotten that eating a food is always risky and such risks can come from processed foods as well as those cooked at home. Decision to ban a particular food has to be taken based on a scientific risk-benefit analysis and not on risk alone. Taking the case of Acrylamide itself, concerns regarding consumer safety are understandable, scaling up the tempo of opposition to fanatical levels is not all justified based on current evidence. Think about thousands of products consumed in India for centuries which were invariably prepared based on raw materials rich in proteins and carbohydrates and probably Acrylamide has been a part of these foods prepared under high temperature conditions for long duration. Baked foods have been in use in western countries since time immemorial and people have not been dying at alarming rate because of cancer. Modern analytical tools have made detection and quantification easier and more accurate but this does not justify raising unnecessary concerns regarding their presence in food.
Now comes a new scare that may rattle the industry further regarding the presence of a new set of chemical artifacts in processed foods and beverages called Furans which are reported to be capable of causing cancer and liver toxicity. Furans refer to a group of chemicals belonging to the group of dioxins and furans. The chlorinated dibenzo furans are implicated in toxicity in animal studies though the levels at which they were used in such experiments are very high. They are formed in foods during processing and being volatile can escape from the finished products by stirring or after a lapse of some time. Oxidation of poly unsaturated fatty acids and similar compounds, decomposition of ascorbic acid derivatives and some carbohydrates can contribute to formation of furans in many foods processed at temperatures beyond 100C. Furans provide typical aroma and taste in many foods and are present in products like roasted coffee powder, canned foods, infant foods, baby foods, puffed rice, fish products, meat products, tomato soups, milk products etc at low concentration levels. Ground coffee can contain Furans as high as 6900 ug per kg while in instant coffee it comes down to 602 ug per kg. Ready to serve coffee beverage can contain about 100 ug of Furans. They are relatively low in milk products like infant foods in the range of 3-40 ug per kg.
Between 2004 and 2009, sustained cooperation amongst some of the countries under a single project generated data on Furans in over 4000 samples belonging to 21 food categories. The reproducability of these data may be tricky because of the high volatility of these chemicals and the possibility of significant reduction of active levels during the interval between opening of the food pack and preparation of test samples. Similarly there can be significant changes in the levels of Furans between original products and preparation of ready to consume final product. It may be reassuring to note the stand of the USFDA which felt that Furans, at this stage does not warrant any concern and cannot be considered as a threat to consumer health. Similarly Canadian Health authorities have taken the stand that present level of knowledge does not call for any change in the dietary practices in that country because of furans in foods.
The million dollar question is whether there should be any concern at all in India where probably people consume foods which are over processed under high temperature conditions. If a product like condensed milk can contain furans at levels of 80 ug per kg, what would be the condition of products like khoa and khoa based products which are made by open kettle heating over long periods or a product like tomato puree made by concentration without vacuum. If poly unsaturated fatty acids are precursors, frying in oils from soy bean and others with high oleic, linoleic and linolenic acids content can contribute to generation of furans. As the information on Furans in Indan foods is not yet available, it may be worthwhile for an institution like National Institute of Nutrition at Hyderabad to look into this area for at least putting the issue at right perspectives.
V.H.POTTY
The Acrylamide "scare" that originated in April 2002 in Sweden by the accidental discovery of the presence of this artifact in some starchy foods processed at high temperatures has assumed hysterical dimension with thousands of reports highlighting its dangerous implication in many human disorders. There are more than 1.5 lakh reports from many countries since 2002 dealing with one or the other aspect of Acrylamide in foods. The WHO and the FAO, as well as health authorities in Europe, the US, Canada etc have come out with safety limits for consumption by human beings. Considering that incidences of cancers in nervous system, oral cavity, peritoneum, thyroid gland, mammary glands and uterus were reported in more than 10% of experimental rats when administered very high doses of Acrylamide, safety experts are invariably cautious in making any recommendation for a safe level of consumption. Currently a daily intake of 1 micro gram per kg body weight is considered safe. Most of the processed foods contain comparatively lower levels of Acrylamide with serving size providing much less than the limit suggested.
Chemically Acrylamide is 2-Propanamide, formed during chemical reaction between fructose, glucose and some reducing sugars with amino acids the most reactive being Asparagine at temperatures beyond 120C. Foods cooked at high temperatures as encountered during roasting, frying, baking etc tend to contain significant levels of Acrylamide, its concentration directly related to the temperature and time of exposure. The fact that it is not stable in acidic or alkaline conditions does allow the GI tract to reduce the impact of its consumption, seems to have been over looked by those crying hoarse about the dangers from Acrylamide. Also under ambient conditions Acrylamide decomposes to Ammonia. According to available data base most affected commercial food products are Potato Chips and French Fries, universally liked by young age consumers including school going children.
Now that a "problem" has been "identified" it is logical that palliative measures are developed to over come the "risks" associated with Acrylamide. The historical fact that potato chips were being consumed for at least during the last 100 years and no "cause and effect" relationship has been established while consuming this product, cannot be brushed away easily and therefore how far this problem is serious must be assessed thoroughly before pronouncing a scientific judgment. The Biotech industry, lately becoming a focus of consumer apprehension because of its role in developing the controversial GM goods, has now jumped into Acrylamide bogey by coming out with bioactive preparations like "Acrylaway", "Preventase" etc based on microbial Asparaginase enzyme derived from molds like A. oryzae, A. niger etc. This enzyme transforms the amino acid Asparagine into a non-reactive entity disabling the Maillard reaction potential very significantly. Use of these enzyme preparations requires the industry to modify the potato chips making process to include a partial frying and steeping steps before the final frying which according to the manufacturers would reduce Acrylamide concentration to the extent of 60-85%. Mandatory approvals have been given for use of Asparaginase enzyme preparations under GRAS category in many countries like the US, some European countries, New Zealand, Australia and China.
It is an irony that "consumer scare" becomes the driving force for spawning a new industry that is supposed to overcome the danger perception amongst the consumers and the policy makers. There are simple ways of handling this perceived problem and consumers can always avoid Acrylamide development in products like potato chips by observing certain precautions like use of potatoes stored at temperatures above 8C, maintaining frying temperatures between 145 and 170C, avoiding prolonged cooking, preferring "golden" tint to dark brown color in the final product and consuming lesser quantities of dark colored fried products as much as possible. Snack industry must increasingly switch over to vacuum frying from the current open frying systems to prevent high temperatures in the frier and consequent generation of Acrylamide in high concentrations in the fried products.
V.H.POTTY