Showing posts with label PET. Show all posts
Showing posts with label PET. Show all posts

Saturday, March 3, 2012

THE "GREEN" BOTTLE-IS IT A MIRAGE?

Fast dwindling fossil fuel reserves make it imperative that their consumption is progressively brought down all over the world and renewable sources of energy are discovered on a a priority consideration. Solar energy, Wind energy, Wave energy, Geothermal energy etc have shown enough promises but requires higher investment and efforts to get translated into commercially viable technologies for mass adoption. Ultimately the cost consideration far outweighs any technological challenge since scientists have enough foundation to come out with technically feasible ideas. So far many of the renewable energy production has been sustained by supportive fiscal policies of many governments but if these alternative options are to be a permanent feature, generation cost and capital cost intensity will have to come down drastically.

Food packaging, intended to give protection to the food inside, has been depending on glass bottles and sanitary cans till about 4-5 decades ago. But there has been a paradigm shift in the packaging industry practices since then with more emphasis on plastics of different types. There are at least a dozen fundamental plastics, most of them polymers, made from petroleum chemicals and with various combinations they provide almost 90% of the packaging resources to the food and pharmaceutical industry. It has not been easy for the packaging industry to win approval of the plastics for packing foods because of the fear of migration of unsafe chemicals that may leach into the food during processing and storage. Well laid down protocols of safety and standard testing practices have made it  possible to get many plastic materials safety cleared during the last two decades.

If plastics are safe and universally acceptable to one and all, plastic industry should have been the happiest lot but one factor that weighs heavily against plastics is their indestructibility and lack of biodegradability. It takes almost 800 years for most plastics to get degraded and even when they are degraded the artifacts produced tend to pollute the environment inviting the wrath of the "Green Movement". Besides recycled plastics do not appear to have all the original functional properties characteristic of the virgin material. Due to innovative policy orchestrations at the level of the governments in many countries, use of plastics is increasingly being frowned upon mainly because of their pollution potential and use of ultra thin films with 20 microns or less are banned in many places. Many shopping malls are charging extra for providing carry bags made from plastics, forcing many consumers to take their own bags for shopping. Of all the plastic materials used by the food and beverage industry Poly (ethylene Terephthalate) commonly known as PET is most conspicuous by its extensive use for manufacture of bottles for soft drinks and bottled water.

PET is a polymer of ethyleneterephthalate monomer and its transparency, physical strength and amenability to easy fabrication, make it eminently suited for bottling operations. Especially its low oxygen permeability allows the content inside immune to oxidative spoilage and consequent quality deterioration. To day almost all soft drinks manufactured in the world are packed in PET bottles. More than 60% of the world production of PET resins is absorbed by the fiber industry for the manufacture of textile yarns while about 30% goes to the bottling industry. As this is derived from petroleum chemicals and their biodegradability credentials are poor, the soft drink industry is strenuously striving to replace these bottles with more sustainable materials. It is true PET bottles do undergo recycling, most of the recycled material going to the carpet industry and some for recycled bottles but still the industry is not happy with its dependence on fossil fuel.     

Beverage bottles, made from PET has two main components. MEG (Mono Ethylene Glycol) makes up about 30 percent of a bottle's weight and it has been possible to make the same from plant sources, especially sugarcane, grown abundantly in Brazil, India and other countries. The other component, called PTA (Purified Tere Phthalic Acid), makes up 70 percent of a bottle's weight. Though scientists have been able to make PTA from plant materials at laboratory level, manufacture on an industrial scale has posed severe challenges. According to recent reports production capacity for MEG is slated to increase dramatically and from one plant producing it to day, there are others getting ready to take up production soon. The environmental groups agitating against plastics are extending massive public support for creating plastics from plant sources as they generate smaller amounts of greenhouse gases, compared to plastics made from petroleum.


A larger issue is whether the world can afford to divert an edible source of food like sugarcane for non-edible packaging materials. Probably a more appropriate approach would be to develop technology for using agricultural waste products, like corn stalks or other materials left over from farming, as feed material for producing plastics. Growing crops for plastic can also cause a lot of land diversion which in turn may affect the price of food to a significant extent. Though some of the beverage giants have declared their intent to use agricultural waste products, such as corn husks, pine bark or orange peels etc, to make its plastic bottles, how far and how long it will take is any body's guess. Regardless of how they are produced, plant based plastics can still create litter and solid waste problems posing another challenge. it is time appropriate legislation is considered for forcing the industry to finance recycling operations and facilitate more increased plastic recycling without creating environmental problems and save water and energy use as much as possible. Considering all these uncertainties, a 100% "green" bottle remains a mirage though in future one cannot rule out dramatic breakthrough in this area.


V.H.POTTY
http://vhpotty.blogspot.com/
http://foodtechupdates.blogspot.com

Monday, February 28, 2011

RECYCLED PLASTICS-FOOD INDUSTRY'S ENLIGHTENED INITIATIVE

Advent of fossil fuel based plastics has literally revolutionized the material foundation of the industrial world and there is no area of manufacturing which is untouched by plastics. Progress in plastic material development has made it possible to make plastics which are as strong as steel while soft plastics find extensive use as containers and bags. Though the convenience and cost factors have pitchforked plastics as the most preferred material of choice till recently, a rethinking about its impact on environment and sustainability is slowly putting a brake on its continued use. While cheap petroleum fuels from which most plastics are derived was justification enough to introduce them in place of traditional materials like glass and metals, this argument cannot hold any more since the cost of non-renewable fossil fuels increased several fold during the last 3 decades.

Plastics attracted severe criticism from the environmentalists because of its lack of biodegradability credentials. It is known that plastic materials take any where from 100 to 1000 years to degrade when used in landfills besides polluting air and water around. Land availability will pose a challenge in many countries if landfill practice is continued and restrictions are now being put in place to curtail this approach. Besides extremely thin plastic bags made from less than 20 micron thick films are choking the drains of many cities causing uncontrolled floods during rainy season. Plastics in garbage are estimated to be killing a million creatures in the sea every year. Littering with plastic bags has become such a nuisance that many countries have banned use of thin plastic bags by the consumer industry during retail sales of products. In some countries incentive schemes are in place for using packaging modes of sustainable nature. Free supply of plastic bags by the retail industry is sought to be discouraged through pricing the same so that consumers are dissuaded from using them. In some countries consumers are encouraged to bring their own bags while many retail stores provide facilities for collection of used plastics for sending to recycling plants.

In India also some of the states are in the forefront in banning plastic bags by grocery stores but implementation lacks the necessary teeth though such a process is bound to take time to assume critical level of efficiency. Surprisingly there is a silent consumer awareness about the adverse impact of plastics on the society and many of them are voluntarily shunning the use on their own without any compulsion. The biggest challenge for the objective of weeding out plastics is posed by lack of infrastructure in most places to segregate plastics from urban wastes generated from the garbage. It is true that in countries in Europe and others like the US there are well designed garbage segregation and collection facilities that enable easy recycling but such an approach is conspicuous by its absence in countries like India and most of the developing world. Unless this is done used plastics will continue to pose problem to the society at large.

While used plastics are often considered a waste, the facts reveal otherwise and it is not realized that throwing a plastic bag has much more connotation than any consumer realizes. Why is that many have come to the conclusion that used plastics must be recycled? There are strong reasons which include constraint on resources, conservation of energy, saving landfill space and avoiding environmental degradation. It is not realized that one ton of plastics, if recycled can save one ton of fossil fuel and it can spare more than 7 cubic meter of land space used for landfill. Recycling thus becomes an economic option and this is realized more by the industry which has led to increased demand for recycled plastics. More and more retailers and branded product companies are in the market looking for high quality recycled plastics. Many of them have already introduced pet bottles containing high percentage of recycled components with less and less virgin polymer. The UK dairy industry is reported to be committed to use up to 50% recycled HDPE in their bottles by 2020. To day about 22% of recycled HDPE plastics is used by the pipe manufacturers while 55% of recycled PET is used by the textile industry. Food industry is slow to catch up with the trend because of the rigid migration limits set for food contact application.

Recycling process is not as simple as one thinks because of the complex chemical and physical science involved in the process. Generally plastics have a low entropy of mixing because of high molecular weight and heating alone cannot ensure dissolving such large molecules. Similarly plastics have to be nearly identical in composition for the process to be efficient as different plastics if melted together can be vulnerable to phase separation with the phase boundaries susceptible to structural weakness. Presence of dyes, fillers and other additives make the recycling process more difficult as the melt becomes too viscous for removing them easily. Beverage bottles and plastic bags, however contain less additives and therefore are preferred for recycling. Sorting out as per Resin Identification Code of the Society of Plastic Industry can make the cycling much more easier.

An added incentive for the industry to look for recycled plastics is the carbon credits they will be able to get by shunning virgin polymeric materials. According to industry sources demand for recycled plastics will far exceed the production that can be achieved by the recycling industry and such a situation will make the recycled products somewhat costlier. Still user industries prefer them because of compulsions to reduce the carbon footprint of the manufacturing and retailing sector as a whole and to achieve increased resource efficiency in the coming years.

V.H.POTTY
http://vhpotty.blogspot.com/
http://foodtechupdates.blogspot.com